Green Economy in the Cement Industry Part 4

The cement plants apart from being an industry that utilizes or processes waste such as slag and fly ash so that a circular economy pattern is formed, is also an industry that destroys waste by using it as fuel. RDF (Refuse Derived Fuel) from municipal solid waste (MSW) is an alternative energy source that is widely used by the cement industry, especially in the manufacture of clinker. In addition to helping overcome environmental problems in the form of environmental pollution from city waste, the use of RDF  also helps reduce carbon emissions or is part of the effort to decarbonize. Related to addressing environmental problems, alternative fuels such as used tires which are chopped into tire chips and plastic are also often used. In addition to these alternative fuels, biomass waste such as agricultural waste and livestock waste are also being used. The biomass waste is 100% renewable fuel, so it is more compatible and environmentally friendly. The use of agricultural waste such as rice husk and camel manure is an example of the use of this biomass waste, for more details, read here.

By operating at high temperatures, the cement plant can function as an effective waste destroyer. In this regard, a DRE (Destruction Removal Efficiency) test is required which must meet a very high score or nearly 100% (99.9999%) to be able to carry out the waste destruction activity. The failure to reach this value is due to the insufficiently high temperature, so the consequence is that not all facilities in the cement plant are able to destroy or burn the waste, only burners in kilns that operate above 1200 degrees Celsius can do it, which technically is waste or alternative fuel also has its own feeding point.

Apart from the power failure, cement plant operations can stop due to blocking. The blocking clogs the cyclone on the preheater and calciner. The main cause of blocking occurs is due to the sulfur content, especially from coal and petcoke or alternative fuels that have a high sulfur content such as tires (tyre chips, the sulfur then reacts with the alkali to form compounds that easily stick to the walls of the cyclone or even the kiln. This means that the percentage of sulfur needs to be limited. And the second cause of blocking is chlorine, which also reacts with alkali so it easily sticks to the walls of the equipment, but the difference is blocking because chlorine occurs at a lower temperature, so it sticks to the top of the cyclone. This means that the percentage of chlorine also needs to be limited.

Based on the conditions mentioned above, the use of alternative fuels, especially from renewable materials, is important, moreover, renewable fuels such as biomass have very low sulfur content, as well as chlorine, but certain alternative fuels must be calculated carefully, especially sulfur and chlorine content. , so no blocking occurs. Meanwhile, fossil fuels such as coal and petcoke apart from being cons of decarbonization efforts also turn out to be the main cause of blocking. This means that the use of fossil fuels must be further reduced.  

Green Economy in the Cement Industry Part 2

A number of cement plants can do production well by using only limestone and clay raw materials. This is because the material has fulfilled all the oxides needed in the manufacture of the clinker. The oxides needed are CaO (C), SiO2 (S), Al2O3 (A) and Fe2O3 (F). Limestone itself usually has a CaO (C) content of around 90% and 5% SiO2 (S). But the facts on the ground are that many cement  plants require additional materials to achieve the desired oxide composition or commonly called corrective materials. A number of these corrective materials are high grade limestone which has a CaO content of above 95% as C oxide correction, then silica sand for S oxide correction, then kaolin or bauxite for A oxide correction and iron ore or pyrite for F oxide correction.

So in general, currently the materials needed for the production of clinker are limestone, clay, silica sand and iron ore. In its development iron ore can be replaced with slag. The content of Fe2O3 (F) slag is lower than iron ore but the price is cheaper. The slag used mainly comes from the iron and steel industry, commonly known as GBFS or GGBFS. Slag is actually also an additive material that can be added with clinker and gypsum so that it becomes a product (slag) cement. In addition to other slag materials such as fly ash which are also commonly used as a additive, these two materials are commonly called cement supplement materials or SCM (supplementary cementious materials). Fly ash which is very fine does not need to be crushed anymore so it can be mixed directly with clinker and gypsum, while slag from iron or steel industry needs to be crushed again into GGBFS before being mixed with clinker and gypsum. For the need for these additives, in addition to physical aspects such as particle size, chemical aspects, namely slag chemistry and fly ash chemistry, are important parameters that need attention.

The use of SCM such as slag and fly ash above, will reduce the use, especially of fossil fuels. This is because SCM is added to clinker and gypsum so it does not require heat energy. Heat energy itself is needed in the manufacture of clinker, namely in the calciner and rotary kiln. For example, the manufacture of slag cement produces 38% less CO2 emissions than the process for the production of portland cement because less limestone is burned for the production of slag cement than is required for Portland cement. This heat energy currently still uses a lot of fossil fuels and is gradually starting to use renewable energy. Energy derived from biomass such as agricultural waste and animal manure is also starting to be used.